England Strikers Kane is believed to have asked to leave Tottenham at the end of the season following another bid not to win the trophy.
The 27-year-old has scored 22 Premier League goals in 2020-21 to leading goal scorer alongside Mohamed Salah, but Spurs are facing a UEFA Champions League qualification.
According to The Times, Barcelona is one of several clubs monitoring the situation with Kane in a bid to take action when the transfer window officially opens.
However, the report indicates that the top striker would like to continue playing in the English Premier League, Chelsea, Manchester United, and Manchester City are all determined.
Tottenham Spurs will unveil to Kane for an estimated £ 150million, said chairman and both chairman Daniel Levy and Kane himself want the situation resolved before Euro 2020 in June.